Notes
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Outline
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CHAPTER 10
  • ENERGY
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10.1 The Nature of Energy
  • The usual definition of energy: the ability to do work
    • Work is moving an object against an opposing force
    • Work = distance × opposing force [ w = d x f ]
    • SI unit of work or energy: the joule (J)
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A joule
  • A joule is the mechanical equivalent of heat meaning the number of units of work which the unit of heat can perform.
  • Its value was found by James Prescott Joule in experiments that showed the mechanical energy which must be expended to raise the temperature of a unit weight of water by 1 degree F. was equivalent to 772 foot-pounds upon the Fahrenheit, thermometric scale, by reason of which it is often called Joule's equivalent, and represented by the symbol J.


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Two basic types of energy

    • Potential Energy: energy of position
      • Examples
        • Boulder on a ledge
        • Cations and anions
        • Chemical bonds



        • Tell how each of the examples above have potential energy.
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Two basic types of energy
    • Kinetic Energy: energy of motion. It depends on the mass and velocity of the object. KE = ½ mv2
    • (where m = mass and
    •           v = velocity)


      • Examples
        • Pool balls
        • Molecules
        • How do each of these have kinetic energy?
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"Chemical Energy - stored energy..."
    • Chemical Energy - stored energy that depends on the composition of the substance.
      • Food and gasoline
    • Nuclear Energy - energy involved in nuclear reactions.
    • Electrical Energy - the chemical reaction that occurs in the battery of a car produces electrical energy used to start the car and operate the headlights, radio, etc.


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There are several forms of energy
    • Light Energy - plants use the radiant energy of sunlight to do the work of making carbon dioxide and water into sugar. This process of creating stored chemical energy is photosynthesis.
    • Mechanical energy – used to do mechanical work
    • Sound Energy
    • Thermal Energy – heat
    • Two things energy is NOT
      • Some sort of invisible fluid
      • Something which can be measured directly

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"Energy can be converted from..."
  • Energy can be converted from one form to another form which is more useful.
  • This occurs all around you on a daily basis. Example: Consider when electrical energy is converted into heat energy in a hair dryer.


  • Give another example of energy conversion


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"A fundamental law governs these..."
  • A fundamental law governs these energy conversions:
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Law of Conservation of Energy
  • in any chemical or physical change, energy is neither created nor destroyed.  (which other law does this remind you of?)


  • Energy may be converted from one form to another but it is always conserved. All the energy involved can be accounted for as work, stored energy, or heat.
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10.2 Temperature and Heat
  • Thermal energy
  • Definition: energy due to chaotic molecular motions
  • Three factors affecting thermal energy
    • Temperature – Definition: a measure of the random motion of the components (atoms/molecules) of a substance
      • Higher temperature leads to higher thermal energy
    • Sample size
      • A cup of hot coffee has more energy than a teaspoon of coffee, all other things being equal.
    • Composition
      • E (solid) < E (liquid) < E (gas), all other things being equal
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Heat
  • Anything that changes temperature, sample size and/or composition of an object can change its thermal energy
  • Heat Definition: transfer of thermal energy due to a temperature difference
  • Thermal energy isn't measurable, but heat is


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Molecular logic time!!
  • Fill in the worksheet as we go through the animations together…
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10.3 Exothermic and Endothermic Processes
  • According to chemistry/physics, when studying reactions etc…  the universe is divided into 2 parts:
    • The System: the part of the universe which you focus your attention.
    • The Surroundings: everything else in the universe.
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Exothermic reaction
  • Energy is lost to the surroundings as heat


  • What examples can you think of?
  • Think of it in terms of motion of particles
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Endothermic reaction
  • Energy is absorbed from the surroundings


  • What examples can you think of?


  • Consider this: If a chemical reaction gives off heat is it endothermic or exothermic?


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Practice:
  • Are the following examples of endothermic reactions or exothermic?
    • Water freezing
    • Ice melting
    • Methane burning
    • Water boiling
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10.4 Thermodynamics
  • Thermodynamics: The study of energy.
  • The Law of conservation of energy is also called the First Law of Thermodynamics: The energy of the universe is constant
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"When we study the heat..."
  • When we study the heat involved in physical and chemical changes there will be two important factors:
    • Amount of heat involved (number)
    • Direction of heat flow (sign)
      • Endothermic change - heat absorbed from the surroundings (q = +)
      • Exothermic change - heat released to the surroundings (q = -)
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To determine the change in energy of a system:
  • DE  = q + w
  • where E is the amount of energy
  • q represents heat
  • w represents work
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10.5 Measuring Energy Changes
  • Thermal energy isn't measurable, but heat is.
  • Measuring Heat involves these units. Calorie and Joule
    •  Calorie: the amount of energy required to raise the temperature of one gram of water one degree Celsius.
      • calorie and Calorie are different. Calorie = 1000 calories. As on food labels
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"Joule can be converted to..."
    • Joule can be converted to calories
      • 1 calorie = 4.184 joules
      • convert 60.1 cal into joules 251J
      • convert 34.8 cal into joules 146J
      • convert 47.3J into cal  11
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Three factors affect how much heat an object absorbs or loses

    • 1. Mass of object
    • 2. Temperature change of object
      • Final temperature minus initial temperature
      • If there is no change in temperature, no heat flows
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"3."
    • 3. Composition of object
      • Specific heat: energy required to raise the temperature of 1 g of material by 1 Celsius
      • Every substance has a specific heat that is unique to itself. The specific heat of water, for example, is 4186 J/ kg x °C (see table on page 297)
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"Specific Heat Capacity is used..."
  • Specific Heat Capacity is used to calculate temperature changes when a substance is heated

  •  Q = m ▪ Cp ▪ ΔT
  • Q or q = Heat Energy in Joules
    m = mass in kilograms
    ΔT = change in temperature (Celsius)
    Cp or s  = specific heat  unit:  joule/ kg x C
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"Example:"
  • Example: How much heat energy is absorbed when 88.0 grams of water is heated from 5.00 degrees Celsius to 37.0 degrees Celsius?  ( c-H2O = 4186 J/ kg x C)
    Take inventory first:
    m = 0.0880 kg ( you must divide by 1000 to convert to kilograms)
    c = 4186 J / kg x C
     ΔT = 32 degrees Celsius ( 37 - 5 = 32)
    Q = ?
  • Q = ( 0.0880)( 4186)(32)
  • Q = 1.18 x 104 J
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Try these examples

      • 100.0 g of water-cools from 30.10°C to 25.05 °C. How much heat is released?
      • 100.0 g of water at 25.00 °C absorbs 100 J of heat. What is its final temperature?
      • A stone weighing 2.0 g absorbs 5.0 J of heat and warms by 3.0 °C. What is the specific heat of the stone? What is the heat capacity of the stone?